Structures with either one, two or all three dimensions on the nanometer scale are of particular interest in solid state physics6. This was confirmed by recording the diffraction patterns at various stages of the melting process of the nanorods. Would you like email updates of new search results? Zelaya-Angel O, Alvarado-Gil JJ, Lozada-Morales R, Varges H, Ferreira da Silva A. Band-gap shift in CdS semiconductor by photoacoustic spectroscopy: Evidence of a cubic to hexagonal lattice transition. Google Scholar. Bacterial metallothioneins: past, present, and questions for the future. 1, pp. Quantum dots in biomedical applications. Hannah, Judith L. Hybrid Nanocomposite Thin Films for Photovoltaic Applications: A Review. 40, no. 59, no. Am. 42714275, 2012. Viana AT, Caetano T, Covas C, Santos T, Mendo S. Environmental superbugs: the case study of Pedobacter spp. 2018;241:104855. Chapter Figure 3d,e shows the TEM image of melted CdS nanorods and corresponding SAED pattern, respectively. Careers. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/. Chestnoy, N., Harris, T. D., Hull, R. & Brus, L. E. J. phys. 308, pp. Citation Yue Gu et al 2019 Chinese Phys. Cadmium sulphide is known for its photocatalytic properties [ 14] which can lead to photodegradation of CdS by oxidation, and formation of cadmium sulphate (CdSO 4 ), cadmium carbonate (CdCO 3) and cadmium oxalate (CdC 2 O 4) [ 15, 16 ]. Anal Chim Acta. Nanomanufacturingperspective and applications. and Article Galaxy Hsu YJ, Lu SY. Front Microbiol. While analyzing the nanorods, the TEM beam current was 80 A at accelerating voltage of 100 kV. Abstract. 8391, 2013. Alivisatos AP. 80, no. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. 2012;15:17383. Article PDF Available. At the same time, theoretical discussion on the shape-property relation predicted that shape anisotropy induced optical polarization and single-particle electronic state differences. 10.1016/0300-483X(93)90111-5 Search in Google Scholar . Cadmium (Cd) is a heavy metal that has a great impact on the environment and can pose a threat to the health of aquatic animals and humans through biological accumulation [1, 2].It is a dangerous trace element due to its acute toxicity and carcinogenicity, so Cd emissions have long been the focus of attention [[3], [4], [5]].According to a recent survey, the Cd content in the . It is naturally occurring in the environment as a pollutant that is derived from agricultural and industrial sources. 1, pp. 85, pp. Thus, prolonged CSNP exposure to an oxidative environment can cause the decomposition of CSNPs, thereby leading to the release of Cd ions. 100, no. This occurrence emphasizes the importance of the Stoer Group as a record of the Mesoproterozoic terrestrial environment. R. Bhattacharya and S. Saha, Growth of Cds nanoparticles by chemical method and its characterization, Pramana, vol. Article R. Wu, C. Wang, J. Shen, and F. Zhao, A role for biosynthetic CdS quantum dots in extracellular electron transfer of Saccharomyces cerevisiae, Process Biochemistry, vol. References Article information Abstract Copper cadmium sulphide thin film was deposited onto glass (soda-lime) substrates using chemical bath deposition (CBD) technique at room temperature. Google Scholar. Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations. Dopant-induced formation of branched CdS nanocrystals. 145151, 2014. Reese, R. N., Mehra, R. K., Tarbet, E. B. 2011;65:29635. Environmentally stable and highly crystalline CdS nanorods have been obtained via a chemical bath method. Zhang H, Yang D, Ma X, Ji Y, Li S, Que D. Self-assembly of CdS: from nanoparticles to nanorods and arrayed nanorod bundles. Triangular CdS Nanocrystals: Synthesis, Characterization, and Stability. Nosenko V, Rudko G, Fediv V, Savchuk A, Gule E, Vorona I. Nanoscale Res Lett. Stokes shift engineering of quantum dots is an attractive approach to enhance luminescence efficiency by reducing reabsorption losses. CIRP Ann. Grill, E., Winnacker, E. L. & Zenk, M. H. FEBS Lett. Terms and Conditions, 199205, 2014. 113, 2010. The corresponding SAED pattern obtained from a field consisting of several tens of nanorods, as shown in Figure Figure2b,2b, is an indication of a highly crystalline zinc blend CdS. Chem. 142146, 2009. Biosynthesis of CdS quantum dots mediated by volatile sulfur compounds released by Antarctic Pseudomonas fragi. Kuczynski, J. Schiermeier Q, Tollefson J, Scully T, Witze A, Morton O. envir. Sci Rep. 2019;9:113. Morphological variations without structural phase transformation are confirmed by recording selected area electron diffraction at various stages. Diaz JG, Planelles J. Lett. 90, 33933399 (1986). The influence of various reaction parameters and solvents on the morphology of CdS nanostructures have been studied extensively by various researchers [14-17]. Photoluminescence spectra of CdS nanorods. The ePub format is best viewed in the iBooks reader. Microbiol. X-ray data indicate that, at this small size, the CdS structure differs from that of bulk CdS and tends towards a six-coordinate rock-salt structure. In recent years, the morphology effect of semiconductor nanocrystallites on their physical properties has aroused extensive attention [12,13]. Petros RA, Desimone JM. 2010 Feb;2(2):168-87. doi: 10.1039/b9nr00415g. The wide band gap, low absorption loss, compact crystallographic cell structure and electronic affinity makes CdS is a promising optoelectronic device for making solar cell CISe and InP .Thin films of CdS have received widespread attention in the direction of other device applications . Spec. your site, Copyright 2023 IOP J. D. Holmes, P. R. Smith, R. Evans-Gowing, D. J. Richardson, D. A. Russell, and J. R. Sodeau, Energy-dispersive X-ray analysis of the extracellular cadmium sulfide crystallites of Klebsiella aerogenes, Archives of Microbiology, vol. The difference in microorganism susceptibility might be attributed to the nature of the cell wall structure, which determines microorganism permeability. Brasier, Martin 2016. Production of H2S and bacterial growth in medium with Cd2+ of the lithobiont collection. Enzyme Microb Technol. S. R. K. Pandian, V. Deepak, K. Kalishwaralal, and S. Gurunathan, Biologically synthesized fluorescent CdS NPs encapsulated by PHB, Enzyme and Microbial Technology, vol. Science (80-). 228244, 2011. The images at higher magnification are shown in Figure 2c,d. 3339, 2017. National Library of Medicine Bruna N, Collao B, Tello A, Caravantes P, Daz-Silva N, Monrs JP, et al. Li Y, Liao H, Ding Y, Fan Y, Zhang Y, Qian Y. Solvothermal Elemental Direct Reaction to CdE (E = S, Se, Te) Semiconductor Nanorod. This is somewhat similar to the CdS nanorod growth reported by Zhang et al [21]. 16S ribosomal DNA amplification for phylogenetic study. Yang JP, Meldrum FC, Fendler JH. In: MATEC web of conferences. Chem Rev. 209214, 2016. Green synthesis and characteristic of core-shell structure silver/starch nanoparticles. Bismuth (Bi) appears to be a metal, but the number of electrons available for electrical conduction is similar to Read More In crystal: Structures of binary crystals 1, pp. Phytochelatins (PCs) are enzymically synthesized peptides produced in higher plants and some fungi upon exposure to heavy metals. Cao BL, Jiang Y, Wang C, Wang WH, Wang LZ, Niu M, Zhang WJ, Li YQ, Lee ST. Synthesis and Lasing Properties of Highly Ordered CdS Nanowire Arrays. It could be concluded that the CdNPs had a greater effect on the gram-positive bacteria than on the gram-negative ones, as indicated by the zone of inhibition (ZOI) values (Table 1), and the CdNPs presented significant antibacterial effect against all the examined bacterial pathogens. 9095, 2009. Higher-order harmonic resonances and mechanical properties of individual cadmium sulphide nanowires measured by in situtransmission electron microscopy Peng Gao, Peng Gao 1 Beijing National Laboratory for Condensed Matter Physics and Institute of Physics Chinese Academy of Sciences Beijing 100190 China Search for other works by this author on: 5563, 1983. Greenlockite Greenockite is a hexagonal, yellowish crystal. 2017. Microbiology. 2016;113:527580. 12351241, 1998. In this paper, we are reporting on a preparation of CdS nanorods and its novel morphological variation under the TEM beam. Thanks for all the adventures and for showing us the beauty of science and friendship. 4, pp. The PL spectra of dispersed CdS nanorods are shown in Figure Figure4,4, with an excitation at 390 nm. Correspondence to A. Sankhla, R. Sharma, R. S. Yadav, D. Kashyap, S. L. Kothari, and S. Kachhwaha, Biosynthesis and characterization of cadmium sulfide nanoparticles an emphasis of zeta potential behavior due to capping, Materials Chemistry and Physics, vol. Introduction. and Charge recombination control for high efficiency quantum dot sensitized solar cells. Fang FZ, Zhang XD, Gao W, Guo YB, Byrne G, Hansen HN. The devices showed an increase in PCE (power conversion efficiency) up to the 3 SILAR cycles, and decreases in PCE were observed for further SILAR cycles. Photocatalytic activities of both CdS . Mbene, K. Orig Life. Chem Phys Lett. 2008 Jul;4(7):951-5. doi: 10.1002/smll.200700787. 16, pp. It occurs in nature with two different polymorphs, cubic hawleyite, and hexagonal greenockite. CAS Thank you for visiting nature.com. Steigerwald, M. et al. 5566, 2015. Chandrangsu P, Rensing C, Helmann JD. Wacey, David 238, no. K. M. K. Selim, I.-K. Kang, and H. Guo, Albumin-conjugated cadmium sulfide nanoparticles and their interaction with KB cells, Macromolecular Research, vol. PubMed These quantum CdS. The melting of nanorods and microstructural transformation to very small nanowires took place without any crystal phase transition. Retardation of nanoparticles growth by doping. Chem. Valizadeh A, Mikaeili H, Samiei M, Farkhani SM, Zarghami N, Kouhi M, et al. G. Chen, B. Yi, G. Zeng et al., Facile green extracellular biosynthesis of CdS quantum dots by white rot fungus Phanerochaete chrysosporium, Colloids and Surfaces B: Biointerfaces, vol. Dunleavy R, Lu L, Kiely CJ, McIntosh S, Berger BW. Yoon SH, Ha SM, Kwon S, Lim J, Kim Y, Seo H, et al. Matheyarasu, R. 7, pp. A precipitated yellow solid product was centrifuged and dried in the oven at 65C for 4 h. The crystal phase analysis of the synthesized nanorods was determined by XRD (Cu K radiation, X'pert, Philips) with a Bragg angle ranging from 20 to 80. Bolan, N.S. 263, 1283212835 (1988). Today's dominant thin-film technologies are cadmium telluride and a more recent competitor, copper indium . 56, no. Int Microbiol. The release of cadmium ions from CSNPs into cell media leads to the surface oxidation of the CSNPs [52]. The authors declare that they have no competing interests. Phase at room temperature: Solid. The bar plots represent the mean optical density (standard deviation, SD) of the experimental conditions, each performed in triplicate. Biomimetic, mild chemical synthesis of CdTe-GSH quantum dots with improved biocompatibility. Yang Z, Gao D, Zhu Z, Zhang J, Shi Z, Zhang Z, Xue D. Nanoscale Res Lett. smCSE (0.1 mg/mL) was incubated with 0.5 mM cadmium acetate and 4 mM l -cysteine in 100 mM Tris buffer (pH 7.5). QE-22, No. J Ind Microbiol Biotechnol. 76, no. Anyone you share the following link with will be able to read this content: Sorry, a shareable link is not currently available for this article. I. Sandoval-Crdenas, M. Gmez-Ramrez, and N. G. Rojas-Avelizapa, Use of a sulfur waste for biosynthesis of cadmium sulfide quantum dots with Fusarium oxysporum f. sp. Thangarajan, R. The nanoparticles (NPs) can be synthesized from agro-waste like Cocos nucifera coir, corn cob, fruit seeds and peels, wheat and rice bran, palm oil, etc. Romaniuk K, Ciok A, Decewicz P, Uhrynowski W, Budzik K, Nieckarz M, et al. 54125416, 2011. A. S. Bhadwal, R. M. Tripathi, R. K. Gupta, N. Kumar, R. P. Singh, and A. Shrivastav, Biogenic synthesis and photocatalytic activity of CdS nanoparticles, RSC Advances, vol. 2006;69(5):48592. Nies DH. Flores 2124, 11800, Montevideo, PC, Uruguay, You can also search for this author in Shatalin K, Shatalina E, Mironov A, Nudler E. H2S: a universal defense against antibiotics in bacteria. The distinguishing characteristics of the inorganic nanoparticle materials have higher surface-to-volume ratios and their nanoscale extent, which enhance the combination with biological pathogens [55]. Yan S, Shi Y, Sun L, Yan W, Zhou M, Hu D, Wu J, Wang J, Shi B, Lan X. J Nanosci Nanotechnol. Similarly, Li et al [25] report the spherical morphology of CdS with cubic Zn-blend structure prepared in water and pyridine at 120C. Development and applications of the heterostructures synthesis based on CdS nanowires. phys. As an important II-VI semiconductor material, CdS nanocrystal has received considerable interest from researchers in control of its morphology and size. Mahanty S, Basak D, Rueda F, Leon M. Optical properties of chemical bath deposited CdS thin films. To find out more, see our, Browse more than 100 science journal titles, Read the very best research published in IOP journals, Read open access proceedings from science conferences worldwide, 2019 Chinese Physical Society and IOP Publishing Ltd, subscriptions at 2016;8:31630. Following this, 0.6 M thiourea solution was slowly added to the mixture with rigorous stirring. A. Azam, A. S. Ahmed, M. Oves, M. S. Khan, S. S. Habib, and A. Memic, Antimicrobial activity of metal oxide nanoparticles against Gram-positive and Gram-negative bacteria: a comparative study, International Journal of Nanomedicine, vol. 2014;13:90. 2011;16(7):101124. Repblica 239, 8370146, Santiago, PC, Chile, V. Carrasco,S. Lagos-Moraga,C. P. Quezada&J. M. Prez-Donoso, Biochemistry and Microbial Genomics Department, Instituto de Investigaciones Biolgicas Clemente Estable, Av. 2017;66:683705. 2019;10:1587. Mandal D, Bolander ME, Mukhopadhyay D, Sarkar G, Mukherjee P. The use of microorganisms for the formation of metal nanoparticles and their application. (b) Relative intensity values obtained from the pixel intensity analysis of the images in a. This letter shows how, by correct orientation of the crystalline axes, mixed or pure modes of vibration can be obtained. CdS nanoparticles are being used widely used for the cancer diagnosis and antimicrobial treatment [ 6, 7 ]. Privacy 2020;10(1):11. 8600 Rockville Pike Cadmium sulphide nanoparticles (CdS) was chosen as a compound of interest due to its high stability, excellent physical, chemical and structural properties, ease of preparation and handling. The solution used was sulfide/polysulfide (S2/Sn2) and it was prepared with 1M Na2S, 0.1M S and 0.1M NaOH dissolved in ultrapure water. Article Nanoscale Res Lett. 163, no. Bacterial synthesis of ternary CdSAg quantum dots through cation exchange: tuning the composition and properties of biological nanoparticles for bioimaging and photovoltaic applications. Most cadmium ore (greenockite): occurs in association with zinc. 5, pp. Plaza DO, Gallardo C, Straub YD, Bravo D, Prez-Donoso JM. An official website of the United States government. Metal homeostasis and resistance in bacteria. Since Klabunde and his coworkers demonstrated that the reactive of metal oxide nanoparticles displays strong antibacterial activity [54], there has been great interest in exploring the use of inorganic nanoparticles as antibacterial materials. Iss. The results obtained from this study confirm that the cadmium-tolerant Aspergillus niger could be considered as an effective, low cost biological source for the biosynthesis of cadmium sulfide nanoparticles. one of the options below. K., Tarbet, E. L. & Zenk, M. H. FEBS.. Leading to the CdS nanorod growth reported by Zhang et al and solvents the., McIntosh S, Basak D, Zhu Z, Gao W, Guo,! Search in Google Scholar approach to enhance luminescence efficiency by reducing reabsorption losses biomimetic, mild chemical of... Competing interests licence, visit http: //creativecommons.org/licenses/by/4.0/ occurs in nature with two different polymorphs, cubic hawleyite, questions... S. 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